On the Options dialog box, click Advanced in the list of items on the left.
In the Outlook start and exit section on the right, click the Browse button to the right of the Start Outlook in this folder box.
On the Select Folders dialog box, all your accounts are listed with their respective folders under them. Select any folder from any account and click the OK button.
Click the OK button on the Options dialog box.
Now, when you open Outlook, your chosen folder will open automatically.
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